With 0–100% TEGDVE/TMPTE, an overall increase in front velocity for samples containing talc was observed with the increasing TEGDVE content, which is an expected trend. 35 At 25% TEGDVE, the front velocity did decrease, which was also observed in previous reports. 35 For samples with hectorite, a front was not supported with 100% TMPTE and no TEGDVE, though a localized reaction occurred upon application of heat.
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Kinetic and Chemical Effects of Clays and Other Fillers in the Preparation of Epoxy-Vinyl Ether Composites Using Radical-Induced Cationic Frontal Polymerization.
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