Monoarsine-protected icosahedral cluster [Au₁₃(AsPh₃)₈Cl₄]⁺: comparative studies on ligand effect and surface reactivity with its stibine analogue.

On the other hand, the correlations of 1D orbitals with the electronegativity of ligands are rather complicated, though they shift to the same direction as 1P orbitals in most cases but lack an obvious trend in the shift amount. 15 In this work, the 1D orbitals in Au 13 As 8 up-shifted more (by 0.156 eV on average) than 1P orbitals (by 0.031 eV on average).

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