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Yttrium- and zirconium-decorated Mg<sub>12</sub>O<sub>12</sub>-X (X = Y, Zr) nanoclusters as sensors for diazomethane (CH<sub>2</sub>N<sub>2</sub>) gas.

RSC Adv · 2023 · PMC10448449 · PMID 37636506

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23 In the adsorption of some small gas molecules such as N 2 O, NO 2 , NO, H 2 S, SO 2 , and SO 3 on Mg 12 O 12 , Be 12 O 12 and Ca 12 O 12 surfaces, the adsorption was observed to follow an increasing trend of Ca 12 O 12 > Mg 12 O 12 > Be 12 O 12 , showing that these gases are fairly adsorbed on the Mg 12 O 12 nanocage. 24 In this present study, investigation was carried out on the adsorption of diazomethane (CH 2 N 2 ) on pure magnesium oxide (MgO) and X-decorated (X = Y and Zr) magnesium oxide (MgO) surfaces.

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