Intermolecular electron transfer in radical SAM enzymes as a new paradigm for reductive activation.

J Biol Chem · 2023 · PMC10470005 · PMID 37460016

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highly significantno p-value reported

To our knowledge, the ability of NADPH to directly reduce FMN or FldA has not been reported previously and may reflect the strictly anaerobic conditions employed in the assays; these results are highly significant as they allow for a new paradigm for the reductive activation of rSAM enzymes.

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