This result is attributed to the metallic substitution reaction, which forms oxygen vacancies in zirconia to maintain electron neutrality [ 28 ]. (1) Z n O → Z r O 2 Z n z r ′′ + O O X + V O • • The interatomic distance between Zr and its first nearest neighbors showed an increasing trend with the increasing ZnO doping level.
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Oxygen Vacancy Ordering and Molten Salt Corrosion Behavior of ZnO-Doped CeYSZ for Solid Oxide Membranes.
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