When comparing the same monodentate phosphine, there is an apparent trend in the magnitude of the trans -coupling constants with dfurpf > dppf > dippf > dcpf > dppdtbpf.
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Cleavage of [Pd<sub>2</sub>(PP)<sub>2</sub>(<i>μ</i>-Cl)<sub>2</sub>][BArF<sub>24</sub>]<sub>2</sub> (PP = Bis(phosphino)ferrocene, BArF<sub>24</sub> = Tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) with Monodentate Phosphines.
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