Exploring the Impact of Elements on the Reactivity of a Straightforward Procedure for Generating Vinyl-Carbazole Derivatives via a Frustrated Lewis Pair Mechanism.

The free activation energy of the former (Δ G ‡ B/G15-TS1 ; kcal/mol), computed relative to its corresponding B/G15-Cpx , demonstrates an increasing trend: 11.0 ( B/Al-TS1 ) < 13.7 ( B/As-TS1 ) < 15.9 ( B/N-TS1 ) < 17.6 ( B/Sb-TS1 ) < 29.5 ( B/Bi-TS1 ).

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