39 Similar to previous results for 3D alkylammonium series, 21 a decreasing trend in T m values with increasing size of the R groups in the A site cation is observed in the 3D compounds, i.e., (EtPh 3 P)[Mn(dca) 3 ] ( T m = 196 °C) < (MePh 3 P)[Mn(dca) 3 ] ( T m = 237 °C).
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(RPh<sub>3</sub>P)[Mn(dca)<sub>3</sub>]: A Family of Glass-Forming Hybrid Organic-Inorganic Materials.
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