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Mechanistic Insights into the Direct Partial Oxidation of Methane to Methanol Catalyzed by Single-Atom Transition Metals on Hydroxyapatite.

ACS Omega · 2025 · PMC11800041 · PMID 39926545

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a decreasing trendno p-value reported
This interaction between adsorbed O 2 molecule and the substrate resulted in elongation of the O–O bond, which followed a decreasing trend of 0.29, 0.28, 0.21, and 0.22 Å from Fe to Cu, suggesting that the degree of activation of O 2 decreases from Fe to Cu.

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