The results indicate an increasing trend in charge transfer when changing the M 3 from Cu( i ) to Au( i ) while keeping the same R substituent.
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Trinuclear cylinder-like potential anticancer and antibacterial Cu(i), Ag(i) and Au(i) nano-sized cationic complexes with tris-NHC ligands: cationic M<sub>3</sub> metal cluster displaying positive or negative cooperativity in triad [L<sub>2</sub>(R)<sub>6</sub>→M<sub>3</sub>]<sup>3+</sup> complexes?
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The sentences
While the R substituent is constant, a decreasing trend in the natural charge was observed by changing the M from Cu( i ) to Au( i ).