Since there is a direct bond between the paramagnetic Ln and 31 P nuclei, CS, PCS, and PSO contributions to the paramagnetic shift are all likely to be significant; conversely, for the shifts of 1 H nuclei in paramagnetic 1-Ln , the PCS term will dominate.
← all excerpts
<sup>31</sup>P NMR Chemical Shift Anisotropy in Paramagnetic Lanthanide Phosphide Complexes.
1
—
—