As shown in Figure S3a , the δ 18 O-H 2 O/δ 2 H-H 2 O values of all samples fell below the global meteoric water line (GMWL, δ 2 H-H 2 O = 8δ 18 O-H 2 O + 10) [ 43 ], indicating an overall trend of evaporation.
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Biogeochemical Mechanisms of HCO<sub>3</sub>-Ca Water and NO<sub>3</sub><sup>-</sup> Pollution in a Typical Piedmont Agricultural Area: Insights from Nitrification and Carbonate Weathering.
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In addition to natural carbonate dissolution, the contribution of agricultural acid (i.e., HNO 3 ) to the equilibrium/supersaturated state of calcite dissolution may be significant due to the large agricultural NH 4 + inputs in the study area [ 28 ], which can accelerate the rate of dissolution from carbonate rocks, thereby improving the equilibrium/supersaturated state of calcite dissolution. 4.2.3.