A number of large red spots are observed in the HS which indicates that short contacts are highly significant in the crystal packing of both compounds.
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Bis(μ-thio-semicarbazide-κ<sup>3</sup> <i>N</i> <sup>1</sup>,<i>S</i>:<i>S</i>;κ<sup>3</sup> <i>S</i>:<i>N</i> <sup>1</sup>,<i>S</i>)bis-[(di-methyl-formamide-κ<i>O</i>)(thio-semicarbazide-κ<sup>2</sup> <i>N</i> <sup>1</sup>,<i>S</i>)cadmium(II)] tetra-kis-(2,4,6-tri-nitro-phen-olate): synthesis, crystal structure and Hirshfeld surface analysis.
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