While the IE a decreases with increasing cluster size, indicating that larger clusters facilitate easier electron detachment, the EA a shows an increasing trend with respect to cluster size, signifying that electron acceptance becomes progressively more favorable as the clusters grow.
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Platinum clusters Pt <sub><i>n</i></sub> <sup>+/0/-</sup> (<i>n</i> = 3-21): from triangles to remarkable tubular architectures.
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