For the Cu(II)–Pyr – complex, the energy gaps are 0.33 eV (ε = 6), 0.40 eV (ε = 40), and 0.51 eV (ε = 78), also exhibiting an increasing trend with a rising dielectric constant.
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A Molecular Mechanism for the Reduction of the Cu Site in Lytic Polysaccharide Monooxygenases by Phenol Reductants.
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