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Highly Selective Synthesis of <i>ctt</i>-1,5,9-Cyclododecatriene from 1,3-Butadiene via Nitrogen-Ligand-Supported Titanium Catalysts: Experimental Optimization and Mechanistic Insights.

ACS Omega · 2025 · PMC12489732 · PMID 41048805

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a decreasing trendno p-value reported
The optimum polymerization temperature was 50 °C, with a monomer conversion of 91% and a catalytic activity of 11.20 × 10 2 g 1,5,9-CDT /(g Ti ·h). When the reaction temperature continued to increase, the monomer conversion did not improve but showed a decreasing trend.

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