Structural Dependence of Catenand Effect: Thermodynamic and Kinetic Modulation of Catenane Coordination Properties via Ring-size and Exocyclic Substituent Variation.

In line with this, a decreasing trend in k scrm of 3.56 × 10 −4 s −1 , 2.00 × 10 −4 s −1 , and 1.82 × 10 −4 s −1 was found for [Cu( C8‐Ms )] + , [Cu( C8‐Ipps )] + and [Cu( C8‐Tipps )] + (Figure S68 ), respectively, with an increasing bulkiness of the exocyclic sulfonamides.

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