Uncovering outer-sphere mechanisms governing chemoselectivity in copper-photocatalyzed ATRA reactions of CF<sub>3</sub>SO<sub>2</sub>Cl with alkenes.

Introduction CF 3 -containing compounds are highly significant for their ability to enhance drug efficacy by increasing lipophilicity, improving bioactivity, and providing greater metabolic stability. 1,2 These properties make them indispensable in pharmaceuticals, agrochemicals, and advanced material development. 3 Consequently, many researchers have focused

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