DPMD simulations, performed on the behavior of U 4+ in the biphasic molten salt system of CsCl-CsF within the temperature range of 500 to 950 °C, indicate that its average coordination number is close to 6, with a decreasing trend as temperature increases, as shown in Supplementary Fig. 3 .
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Incorporation of uranium to the langbeinite family in Cs<sub>2</sub>U<sup>Ⅳ</sup>Ln(PO<sub>4</sub>)<sub>3</sub> actinide waste forms.
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