Oxidant-Dependent Switch of a Molybdenum(VI) Tetrazolate Complex from a Homogeneous to a Self-Separating Catalyst for Olefin Epoxidation.

The only exception is the hexamolybdate, which performed slightly better in the epoxidation of MO, giving 97% epoxide yield after 3 h (entry 21) vs 94% at 4 h in the case of 1 (entry 12), but this difference may not be significant in the light of the different initial TBHP:MO ratios used.

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