Due to the significant phonon localization at higher temperatures, κ p decreases with temperature following T - 1 relationship, while κ c shows an increasing trend resulting in a particle-to-wave-like crossover at 175 K.
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Anharmonicity driven unusual particle-to-wave-like phonon crossover leads to ultralow thermal conductivity in Tl<sub>2</sub>AgI<sub>3</sub>.
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