Electrochemical Water Oxidation Mechanisms Involving Macrocyclic Copper(II) Complexes: Ligand Ring Size Effects on Catalytic Cycles.

Chemphyschem · 2026 · PMC12931582 · PMID 41371263

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a possible trendno p-value reported

Regarding the O—O bond formation process, we noticed a possible trend that the reaction barrier of the SET–WNA mechanism turns slightly higher with the reduction of the ligand size.

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