The electronic bandgap reveals an increasing trend as the A-site is replaced by K → Rb → Cs, revealing indirect bandgaps of 2.80 eV, 2.78 eV and 3.10 eV for K 2 AlCuF 6 , Rb 2 AlCuF 6 and Cs 2 AlCuF 6 , respectively.
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Bandgap tuning through the substitution of alkali metal cations in A<sub>2</sub>AlCuF<sub>6</sub> (A = K, Rb, and Cs) for optoelectronic and renewable energy applications.
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