Taming Flexibility: Synergistic Pore and Polarity Engineering in a MOF for High-Efficiency Xe/Kr Separation.

Adv Sci (Weinh) · 2026 · PMC13336414 · PMID 42295807

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a decreasing trendno p-value reported

PLATON calculations reveal a decreasing trend in accessible solvent volume: ZIF‐7 (26.6%) > ZIF‐7‐Cl(20) (24.6%) > ZIF‐7‐Cl(100) (18.5%), clearly demonstrating the pore‐constricting effect of chlorine substitution.

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