Attempts to isolate the CF 3 SO 2 – salt of [V V O(pb)] + and to bind [V V O(pb)] + to a cation-exchange resin from 1 to 2 day-old solutions of V(IV) and pbH 2 were unsuccessful, which indicates that the concentration of [V V O(OH)(pb)] may be significant over time periods <15 months.
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Complexes formed in solution between vanadium(IV)/(V) and the cyclic dihydroxamic acid putrebactin or linear suberodihydroxamic acid.
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