While the experimental gas-phase UV-PES data of the indole molecules do not show a particular trend with regard to the first IE, electrochemistry data in solution phase reveal a small trend with regard to the anodic peak potential (lowest to highest): external BN indole I (0.95 V) < fused BN indole II (1.05 V) < natural indole (1.22 V).
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UV-photoelectron spectroscopy of BN indoles: experimental and computational electronic structure analysis.
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