Discovery of Dark pH-Dependent H(+) Migration in a [NiFe]-Hydrogenase and Its Mechanistic Relevance: Mobilizing the Hydrido Ligand of the Ni-C Intermediate.

18 It may be significant, as discussed later, that Hyd-1 is an O 2 -tolerant [NiFe]-hydrogenase, a special class that can operate in the presence of O 2 that differs from “standard” (O 2 -sensitive) [NiFe]-hydrogenases mainly in the composition and reduction potentials of Fe–S clusters in the electron relay. 19 − 26 The O

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