Upon CO exposure at 323 K, the CN value for Rh–Rh seems to be constant; however, at elevated temperatures of 423–573 K, a decrease in CN Rh–Rh of about 1 can be observed, which is barely significant.
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Time-resolved, in situ DRIFTS/EDE/MS studies on alumina-supported rhodium catalysts: effects of ceriation and zirconiation on rhodium-CO interactions.
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