This is because the interplanar distance between the two platinum( ii ) terpyridine moieties of the dimeric structure is found to be 3.47 Å, which suggests weak to almost insignificant Pt···Pt interactions in the polymeric zigzag chain structures.
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Supramolecular assembly of a phosphole-based moiety into nanostructures dictated by alkynylplatinum(ii) terpyridine complexes through non-covalent Pt···Pt and π-π stacking interactions: synthesis, characterization, photophysics and self-assembly behaviors.
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