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A new twist in the photophysics of the GFP chromophore: a volume-conserving molecular torsion couple.

Chem Sci · 2018 · PMC5892128 · PMID 29675225

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In this connection, the recent characterization of a key role for the electrostatic environment of the chromophore in controlling photoprotein fluorescence yield may be significant. 73 Conclusions We have synthesized a novel nonplanar form of the GFP chromophore, I , and investigated its photophysics.

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