Recently we have started exploring the link between ᾱ and low-energy (ground state) photoionization cross-sections, revealing a highly significant positive linear correlation that has previously proved instructive in the interpretation of TRPEI data. 5 , 46 It is therefore interesting to note that ᾱ for the 3s state is ∼2–4 times larger than that obtained for the members of the 3p manifold.
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The role of novel Rydberg-valence behaviour in the non-adiabatic dynamics of tertiary aliphatic amines.
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