The M–O–C bond angles for the amide solvated alkaline earth metal ions deviate largely but with a weak trend in the order Mg 2+ < Ca 2+ ≈ Sr 2+ > Ba 2+ , Table S2b (ESI † ), showing that more space becomes available with increasing ionic radius.
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On the relationship between the structural and volumetric properties of solvated metal ions in O-donor solvents using new structural data in amide solvents.
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