3 , 4 Due to the octahedral geometry of the R-SF 4 -R′ moiety, the trans -SF 4 configuration has the ability to function as a building block in the construction of linear structures via its axial bonds, which makes the trans -SF 4 configuration highly significant. 3 , 4 The rod-like connection by the trans -SF 4 unit potentially suggests new approaches for designing novel pharmaceuticals, while also leading to sought-after fluorine-containing drug candidates.
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An eccentric rod-like linear connection of two heterocycles: synthesis of pyridine <i>trans</i>-tetrafluoro-λ<sup>6</sup>-sulfanyl triazoles.
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