Similarly, since the chain tension increases rapidly for small chains a force-dependent chain dissoication rate would be highly significant for high cross-linker concentrations.
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The Chain Distribution Tensor: Linking Nonlinear Rheology and Chain Anisotropy in Transient Polymers.
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The sentences
The viscosity measurements indicate an increasing trend with higher cross-link densities as shown in Figure 5 a, which have been fitted with our model using Equation ( 10 ) with chain concentration, C , number of Kuhn segments in the chain N and different values of k d for the varying cross-linker concentration.