Because this is many orders of magnitude larger than the rate of the H-shifts, or of bimolecular reactions with trace gases, the lack of interest in the specifics of the O 2 addition reaction is understandable. However, there are some notable cases for which the exact kinetics of the O 2 + alkyl reaction may be significant.
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Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol.
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