Structural Characteristics, Population Analysis, and Binding Energies of [An(NO₃)]²⁺ (with An = Ac to Lr).

The decrease in the An–O1 bond length and increase in O1–An–O2 angle in [An(NO 3 )] 2+ across the actinide presents discontinuities in An–O1 distance for [Fm(NO 3 )] 2+ , [Md(NO 3 )] 2+ , and [No(NO 3 )] 2+ , which showed a longer bond length and smaller angle in the gas phase due to being in an An III state instead of An IV. However, for solvated structures, an overall trend is followed from Ac to Md but not for No, which has an An III configuration in [No(NO 3 )] 2+ both in gas and solution when calculated with the methods included in this study.

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