Flory [ 37 , 38 ] and Huggins [ 39 ] demonstrated that the entropic law that governs the immiscibility of low molecular weight (LMW) compounds (Δ G m = Δ H m − T Δ S m ) becomes an almost insignificant contributing factor for high molecular weight (HMW) materials, with an increase in molar mass leading to a decrease in Δ S m resulting in Δ G m > 0.
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Effect of Polymer Demixed Nanotopographies on Bacterial Adhesion and Biofilm Formation.
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