The Ba 2+ /Pb 2+ −O3 bond also exhibits an increasing trend (Fig. 5b ).
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Unprecedented lattice volume expansion on doping stereochemically active Pb<sup>2+</sup> into uniaxially strained structure of CaBa<sub>1-x</sub>Pb<sub>x</sub>Zn<sub>2</sub>Ga<sub>2</sub>O<sub>7</sub>.
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