Ultrafast Vibrational Energy Transfer between Protein and Cofactor in a Flavoenzyme.

The largest KIEs are on the first lifetime, τ 1 (the major FMN excited state relaxation component). The second two lifetime components, τ 2 and τ 3 , which are assigned, at least partially, to transfer vibrational energy to the protein and subsequent relaxation, show smaller KIEs, and the only KIE that may be significant is the protein 13 C KIE on τ 2 .

also in 13,097 other papers

While the uncertainty in the kinetic fit parameters means that many of the apparent KIEs may not be significant, there are some noticeable trends.

also in 2,774 other papers