Thermodynamic aspects of complex coacervation have been covered extensively by others, 7 − 18 to which we refer the interested reader for a more in-depth description. Briefly, both enthalpic and entropic contributions may be significant, each of which depends markedly on the ionic strength of the solution.
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100th Anniversary of Macromolecular Science Viewpoint: Attractive Soft Matter: Association Kinetics, Dynamics, and Pathway Complexity in Electrostatically Coassembled Micelles.
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