7 Results and Discussion General Trends According to the pioneering work of Beijerinck and co-workers, 21 molecular systems giving CHEMI, all experimentally investigated in detail in the gas phase under single collision conditions with the molecular beam technique, can be distinguished in two groups: CHEMI systems showing a pronounced increase in the total ionization cross section as E coll increases and CHEMI systems showing, contrariwise, cross sections with a decreasing trend.
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Chemi-Ionization Reactions and Basic Stereodynamical Effects in Collisions of Atom-Molecule Reagents.
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