In rough approximation, the rate constant k Z → E is higher in non-polar solvents compared to polar solvents, while the equilibrium E / Z ratio exhibits only a weak trend in solvent polarity.
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Solvent-controlled <i>E</i>/<i>Z</i> isomerization <i>vs.</i> [2 + 2] photocycloaddition mediated by supramolecular polymerization.
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