Solvent and Temperature Effects on Photoinduced Proton-Coupled Electron Transfer in the Marcus Inverted Region.

For large ranges of temperature, the variation of Δ G ° and λ with temperature may be significant, which is attributed to the reaction entropy and reorganization entropy, respectively. 48 − 50 The CSS is a zwitterionic species that polarizes the solvent, resulting in a smaller entropy than for the charge neutral LES and GS.

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