Van Der Waals gap-rich BiOCl atomic layers realizing efficient, pure-water CO₂-to-CO photocatalysis.

We also observed increasing trends in the intensities of the FTIR peaks of the *COOH group (1196 and 1541 cm −1 ) and the CO molecule (2017 cm −1 ), in addition to a decreasing trend in the FTIR intensity of CO 2 (2280–2340 cm −1 ) (Fig. 4e and Supplementary Figs. 53 – 55 ), thereby supporting the above-simulated reaction pathways.

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