Photocatalytic Arylation of P₄ and PH₃ : Reaction Development Through Mechanistic Insight.

[9b] Given that Et 3 N is widely used as a “privileged” terminal reductant in photoredox transformations, and that [ 1 ]PF 6 and 2 have also been used to catalyse many other photoredox reactions, these results suggest that similar patterns of non‐selective side‐reactivity could be an underappreciated but highly significant limiting factor in many other photoredox transformations (indeed, related non‐innocent side reactions have previously been highlighted in some other catalytic reactions).

also in 132,142 other papers