49 Although the percentage of Si–O–Si connection decreases with increased P content, DPC SiSi has an increasing trend, indicating that P obviously improves the priority of Si–O–Si linkage, especially for LAP compositions, suggesting the formation of separated silicon–oxygen rich regions, which could induce the emerging of cristobalite (SiO 2 ) crystals after heat treating. 50 Such complex bonding geometries might
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A modified random network model for P<sub>2</sub>O<sub>5</sub>-Na<sub>2</sub>O-Al<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub> glass studied by molecular dynamics simulations.
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