Zinc insertion in the non-peripheral series ( 3 and 4 ) has a marginally significant influence on the binding energy of N meso (397.7 − 398.3 = −0.6 eV), whereas both zinc and magnesium insertion into the peripheral series (i.e., comparing 8 with 6 and 7 ) has a negligible N meso binding energy difference.
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Octakis(dodecyl)phthalocyanines: Influence of Peripheral versus Non-Peripheral Substitution on Synthetic Routes, Spectroscopy and Electrochemical Behaviour.
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