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Covalency in actinide(iv) hexachlorides in relation to the chlorine K-edge X-ray absorption structure.

Chem Sci · 2022 · PMC8926251 · PMID 35414875

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an increasing trendno p-value reported
S1 (UKS), † from [ThCl 6 ] 2− to [PuCl 6 ] 2− , is in apparent contradiction with the NPA and BO data and therefore the AO mixing in these MOs does not reflect an increasing trend in 5f covalency going from Th to Pu.

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