Firstly, when calcination temperature was raised from 450 to 550 °C, the band gap energy showed a decreasing trend from 2.77 to 2.72 eV, this could be because of increased degree of polymerisation of g-C 3 N 4 , resulting in increase of π-plane conjugation degree of heptazine rings via N 2 atoms. 42 When temperature was further raised to 650 °C, a blue shift in absorption edge was observed and band gap energy increased to 2.83 eV.
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Effect of calcination temperature, pH and catalyst loading on photodegradation efficiency of urea derived graphitic carbon nitride towards methylene blue dye solution.
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