As X varies from F to I, the thermodynamic stabilities of both XAuCN and XAgCN increase due to the increasing Δ E 1 , while the thermodynamic stability of XCuCN shows a decreasing trend.
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An <i>ab initio</i> study on coinage atom-inserted cyanide/isocyanide: XMCN/XMNC (M = coinage atoms; X = halogen).
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